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tance. This study systematically investigated the photocatalytic activity of dissolved state biochar (DSB) with different pyrolysis temperature to the degradation of atorvastatin (ATV), a medicine widely used to combat hyperlipidemia. It was found that the photocatalytic efficiency of DSB increased with the decrease of pyrolysis temperature, that is, DSB300 (DSB with 300 °C of pyrolysis temperature) had the greatest photocatalytic activity in same condition, which was attributed to the dual role of DSB300 as heterogeneous photocatalyst and photosensitizer. The mineral components were responsible for the heterogeneous photocatalytic activity of DSB300. Organic carbon components could synergistically enhance the heterogeneous photocatalytic activity by enhancement of electron-hole separation, and contribute to the formation of singlet oxygen (1O2) and triplet-excited state (3DSB*) as well. The identification of intermediate products and X-ray photoelectron spectroscopy (XPS) analysis of irradiated DSB300/ATV revealed that cross-coupling reaction between ATV and DSB existed in the photodegradation process of ATV. The detailed photodegradation pathways of ATV were proposed, which was triggered by oxygen insertion of pyrrole ring and hydroxyl addition. Meanwhile, the modification of DSB300 under irradiation was evidently attenuated with ATV as shown by multiple characterizations, which helped to keep the stability of DSB300 in photochemical reaction process. The mobility of Cr(VI) in the environment is affected by the transformation of ferrihydrite (Fh) and ferrihydrite-humic acid co-precipitates (Fh-HA). However, the impacts of Fe(II)-induced transformation of Fh and Fh-HA on the mobility, speciation and partitioning of associated Cr(VI) remain unclear. In this study, the behaviors of adsorbed Cr(VI) during Fh and Fh-HA aging at 70 °C for 9 days (pH0 = 3.0 and 7.0) in the absence and presence of Fe(II) were studied. Results revealed that the main speciation of Cr(VI) after transformation was non-desorbable Cr and its formation involved the following pathways. Firstly, Fe(II) (0.2 and 2.0 mM) induced the transformation of Fh-HA to hematite and goethite, promoting the structural incorporation of adsorbed Cr into hematite and goethite via complexation. Secondly, under neutral condition (pH0 = 7.0), the low concentration of Fe(II) (0.2 mM) could not reduce completely Cr(VI) to Cr(III) and thus residual Cr(VI) was incorporated into the Cr(III)-Fe(III) co-precipitates. Thirdly, coprecipitated humic acid not only reduced Cr(VI) to Cr(III) via polysaccharide, but also formed complexes with incorporated Cr through carboxylic groups to sequester Cr. Our results demonstrate that Fe(II)-induced transformation of Fh-HA exerts major influences on associated Cr(VI) speciation and partitioning. Aiming at SO2 and NOx in industrial flue gas, the simultaneous removal of SO2 and NOx was conducted using red mud as absorbent with O3 oxidation. The effects of different factors on the desulfurization and denitration efficiency were investigated. The results show that the increase of oxidation temperature is not conducive to the absorption of NOx (O3/NO molar ratio >1). Low concentration of SO2 promotes the absorption of NOx, however high concentration of SO2 inhibits absorption of NOx. The main product after desulfurization and denitration of red mud solid residue is bassanite (CaSO4·0.5H2O). In addition, when the pH is greater than 5, calcium carbonate and sodium alkali play major roles in red mud, and when 3.5 less then pH less then 5, sodium aluminosilicate hydrate (1.08Na2O·Al2O3·1.68SiO2·1.8H2O), calcium nepheline (Na6CaAl6Si6(CO3)O24·2H2O) and garnet (Ca3Al2(SiO4)(OH)8) take part in the reaction. According to typically practical conditions with oxidation temperature at 130 °C and the O3/NO molar ratio being 1.8, the desulfurization efficiency of red mud can reach 93 % in the first hour, and the denitration efficiency can be maintained at about 87 %. Besides, the reaction mechanism with multi oxidation absorption steps was also proposed. Antibiotic resistance genes (ARGs) are serious pollutants in municipal sewage treatment plants and may cause significant harm to ecological systems, microbial fouling is also inevitable in membrane process. Herein, novel forward osmosis (FO) membranes made of electrospun nanofibers (TFN0) and further impregnated with titanium dioxide (TiO2) (TFN1) nanoparticles and titanium dioxide/silver composite nanoparticles (TiO2/AgNPs) (TFN2). The FO membranes were used to compare the antimicrobial performance and rejection of tetracycline-resistant genes (TRGs). Characterizations revealed that the TiO2/AgNPs were evenly scattered in the polysulfone (PSf) nanofibers and resulted in a TFN2 membrane that exhibited excellent physicochemical properties, filtration, and antibiofouling performance in real wastewater. The cell viability analysis revealed that the antibacterial effect of the TFN2 membranes was significantly better than that of TFN1, as indicated by about 65 % of E. coli cells killed after contact with the TFN2 membrane. TFN2 membranes had greater rejection rates of TRB and TRGs than TFN1. The TRG permeation rates of the TFN2 membrane in the FO mode (active layer facing the feed solution) were 39.62 % and 33.02 % lower than the TFN0 and TFN1 membranes, respectively. FO membranes modified by the TiO2/AgNPs nanocomposites hold promise to remove ARGs and pathogens from wastewater treatment plant effluents. Local government's environmental expenditure (LGEE) is critical to ecological protection and environmental governance, and it has not played its due role. By constructing a theoretical model of the competitive effect of LGEE under the intervention of central government, this study used the spatial econometric model to analyze the competitive effect of LGEE based on the data of 30 provinces in China from 2007 to 2016. The main results show that (1) from the perspective of the national area, LGEE shows a U-shaped development model together with economic growth; (2) a significant positive spatial effect in interprovincial LGEE is observed in eastern region, indicating that local government tends to adopt the competitive strategy of mutual imitation. Local government will not reduce environmental expenditure as fiscal decentralization increases; (3) the coefficient of the spatial effect in LGEE is significantly negative in central and western regions, which is manifested as a competitive strategy of mutual substitution. The coefficient of fiscal decentralization is significantly negative, indicating that LGEE relies mainly on the transfer payments from central government, and the essence of interprovincial competition regarding environmental expenditure is the competition for the transfer payments from central government. Trace metals and nutrients attached on road deposited sediments (RDS) are the main source of non-point pollution to urban waterbodies causing ecological degradation and eutrophication problems. Mathematical models of the pollutant build-up process on road surfaces can be used to develop remediation measures. However, there was lack of research on the pollutant build-up process of various sized particles during a long dry period. This research investigated the build-up behaviors of specific pollutants in size-fractioned particles during 41 antecedent dry-weather days (ADDs), which was the longest build-up period ever studied. This research revealed that the pollution concentration exhibited a mono-growth behavior, while the pollutant mass followed a cyclic behavior during the study period. The time to peak and the build-up cycle of various pollutant mass were all highly associated with the particle characteristics, and the mass and concentration levels of pollutants in various sized particles were different. Furthermore, two important phenomena were found in this study the bioavailability of phosphorus as well as the enrichment factors of metals all increased along with time during the build-up process. These findings provide new insights in non-point source pollution build-up and improve the water quality modelling. Ordered mesoporous carbon (CMK-3) supported nanoscale zero-valent iron (nZVI) composites were synthesized and used for the removal of trichloroethylene (TCE). The nZVI/CMK-3 composites exhibited high TCE removal efficiency in a batch study, which was 2.5 times that of nZVI alone. They also displayed excellent reusability, with 65.2% removal efficiency after three treatments. Dechlorination dominated the process of TCE removal (75.3%-79.4%), whereas adsorption accounted for 20.6%-24.7%. CMK-3 enhanced the dechlorination rate and efficiency of TCE by nZVI, and the enhancement was favored with the increase in CMK-3 content. The Tafel analysis and H2 evolution experiments indicated the mechanisms of CMK-3 action in nZVI/CMK-3 composites for TCE removal. CMK-3 serves as a direct electron transfer, whereas CO was identified as the functional group involved; the other involved the acceleration of redox reaction of atomic hydrogen owing to the superior hydrogen adsorption capacity of CMK-3. The present study provides new perspectives for seeking more efficient nZVI to reinforce the dechlorination process; however, more studies are warranted in the long-term performance of nZVI/CMK-3 in the aquifer condition. Plastic waste is an environmental burden substance, which poses a high threat to the society during disposal. Rather than disposal, recycling of this waste to liquid fuel gains importance owing to its high utility. Among various techniques, thermo-chemical recycling techniques hold more benefits in generating high value added liquid fuels. In this review, the details of municipal plastic waste generation are provided with a brief description of the plastic waste management option and importance of recycling is explained. The overview of the thermo-chemical treatment focusing on the pyrolysis, gasification and hydrocracking process was elaborated. Catalysts mediated pyrolysis have wide-open their prospective for the generation of bio-oil, hydrocarbons, syngas and deterioration of undesired substances. Generally, advance development of enthusiastic catalysts for the synthesis of bio-oil would be vital for scaling up the pyrolysis process to succeed in commercial manufacture of biofuels from waste plastics. Overall rate treatment depends on operating parameter which determines the process efficiency and product yield. Hence, critical assessment of various parameter that has remarkable effect in the thermo-chemical treatment process was documented in detail. Moreover, endorsements of liquid fuel production, economic viability, and energy requirement of the treatment process, were delivered to attain effectual plastic wastes management. V.Despite knowing the phytotoxic effects of tropospheric ozone (O3), which is of global concern, there is no study so far reported about its impacts on grassland community of tropical regions. Therefore, we assessed the responses of a semi-natural grassland community of Indo-Gangetic plains to elevated O3 exposure (Ambient + 20 ppb) compared to ambient after three years of exposure using open-top chambers. Percent decreases were found in above (26%; p ≤ 0.002) and belowground (30%; p ≤ 0.003) biomass under elevated compared to ambient O3 exposure. Percent decrements in total organic carbon (TOC; 24%; p ≤ 0.001), total nitrogen (29%; p ≤ 0.001) and available phosphorus (11%; p ≤ 0.002) in the soil were also observed under elevated O3 exposure. Exposure at elevated O3 reduced soil microbial biomass and activities of β-glucosidase, amylase, urease and phosphatase, while polyphenol oxidase and peroxidase showed enhancement in their activities, showing negative effects on belowground soil health. https://www.selleckchem.com/products/brensocatib.html Percent reduction in root shoot ratio (10%; p ≤ 0.
